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Faculty of Biology, Chemistry and Earth Sciences

Chair of Inorganic Active Materials for Electrochemical Energy Storage - Prof. Bianchini

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Publications

2024

K-Doping Suppresses Oxygen Redox in P2-Na₀.₆₇Ni₀.₁₁Cu₀.₂₂Mn₀.₆₇O₂ Cathode Materials for Sodium-Ion Batteries
Bei Zhou, Deniz Wong, Zhongheng Fu, Hao Guo, Christian Schulz, Guruprakash Karkera, Horst Hahn, Matteo Bianchini, Qingsong Wang
Small, 2024

Improved Performance of High‐Entropy Disordered Rocksalt Oxyfluoride Cathode by Atomic Layer Deposition Coating for Li‐Ion Batteries
Bei Zhou, Siyu An, David Kitsche, Sören L. Dreyer, Kai Wang, Xiaohui Huang, Jannik Thanner, Matteo Bianchini, Torsten Brezesinski, Ben Breitung, Horst Hahn, Qingsong Wang
Small Structures, 5, 2024

New insights into aging in LiNiO₂ cathodes from high resolution paramagnetic NMR spectroscopy
H. Nguyen, P. Kurzhals, Matteo Bianchini, K. Seidel, R. J. Clément
Chemical Communications, 60, 4707-4710: 2024

Off-Stoichiometry, Vacancy Trapping, and Pseudo-irreversible First-Cycle Capacity in LiNiO₂
Sabrina Sicolo, Marcel Sadowski, Kilian Vettori, Matteo Bianchini, Jürgen Janek, Karsten Albe
Chemistry of Materials, 36, 492-500: 2024

Phase stability and charge compensation in disordered rock salt compounds based on nickel and titanium
Agnese Reitano, Sylvia Kunz, Mingfeng Xu, Emmanuelle Suard, Matteo Bianchini
Journal of Materials Chemistry A, 12, 15731-15743: 2024

2023

In situ neutron diffraction to investigate the solid-state synthesis of Ni-rich cathode materials
Damian Goonetilleke, Emmanuelle Suard, Benjamin Bergner, Jürgen Janek, Torsten Brezesinski, Matteo Bianchini
Journal of Applied Crystallography, 56, 1066-1075: 2023

A novel solid-state synthesis route for high voltage Na₃V₂(PO₄)₂F₃₋₂ᵧO₂ᵧ cathode materials for Na-ion batteries
Mainul Akhtar, Hafssa Arraghraghi, Sylvia Kunz, Qingsong Wang, Matteo Bianchini
Journal of Materials Chemistry A, 11, 25650-25661: 2023

Stoichiometry matters: correlation between antisite defects, microstructure and magnetic behavior in the cathode material Li₁₋zNi₁₊zO₂
Damian Goonetilleke, Björn Schwarz, Hang Li, Francois Fauth, Emmanuelle Suard, Stefan Mangold, Sylvio Indris, Torsten Brezesinski, Matteo Bianchini, Daniel Weber
Journal of Materials Chemistry A, 11, 13468-13482: 2023

Twin Boundaries Contribute to The First Cycle Irreversibility of LiNiO₂
H. Nguyen, R. Silverstein, A. Zaveri, W. Cui, P. Kurzhals, S. Sicolo, Matteo Bianchini, K. Seidel, R. J. Clément
Advanced Functional Materials, 2023

Atomic Layer Deposition Derived Zirconia Coatings on Ni‐Rich Cathodes in Solid‐State Batteries : Correlation Between Surface Constitution and Cycling Performance
David Kitsche, Yushu Tang, Hendrik Hemmelmann, Felix Walther, Matteo Bianchini, Aleksandr Kondrakov, Jürgen Janek, Torsten Brezesinski
Small Science, 3, 2023

The Effect of Single versus Polycrystalline Cathode Particles on All‐Solid‐State Battery Performance
Seyedhosein Payandeh, Christian Njel, Andrey Mazilkin, Jun Hao Teo, Yuan Ma, Ruizhuo Zhang, Aleksandr Kondrakov, Matteo Bianchini, Torsten Brezesinski
Advanced Materials Interfaces, 10, 2023

Probing the Ni(OH)₂ Precursor for LiNiO₂ at the Atomic Scale : Insights into the Origin of Structural Defect in a Layered Cathode Active Material
Anuj Pokle, Daniel Weber, Matteo Bianchini, Jürgen Janek, Kerstin Volz
Small, 19, 2023

2022

Advanced Nanoparticle Coatings for Stabilizing Layered Ni‐Rich Oxide Cathodes in Solid‐State Batteries
Yuan Ma, Jun Hao Teo, Felix Walther, Yanjiao Ma, Ruizhuo Zhang, Andrey Mazilkin, Yushu Tang, Damian Goonetilleke, Jürgen Janek, Matteo Bianchini, Torsten Brezesinski
Advanced Functional Materials, 32, 2022

Advances and challenges in multiscale characterizations and analyses for battery materials
Matteo Bianchini, Valentina Lacivita, Dong-Hwa Seo, Haegyeom Kim
Journal of Materials Research, 37, 3113-3129: 2022

Alleviating Anisotropic Volume Variation at Comparable Li Utilization during Cycling of Ni-Rich, Co-Free Layered Oxide Cathode Materials
Damian Goonetilleke, Felix Riewald, Aleksandr Kondrakov, Jürgen Janek, Torsten Brezesinski, Matteo Bianchini
The Journal of Physical Chemistry C, 126, 16952-16964: 2022

Deeper Understanding of the Lithiation Reaction during the Synthesis of LiNiO₂ Towards an Increased Production Throughput
Philipp Kurzhals, Felix Riewald, Matteo Bianchini, Shamail Ahmed, Andreas Michael Kern, Felix Walther, Heino Sommer, Kerstin Volz, Jürgen Janek
Journal of the Electrochemical Society, 169, 2022

The interplay between (electro)chemical and (chemo)mechanical effects in the cycling performance of thiophosphate-based solid-state batteries
Jun Hao Teo, Florian Strauss, Felix Walther, Yuan Ma, Seyedhosein Payandeh, Torsten Scherer, Matteo Bianchini, Jürgen Janek, Torsten Brezesinski
Materials Futures, 1, 2022

The LiNiO₂ Cathode Active Material : A Comprehensive Study of Calcination Conditions and their Correlation with Physicochemical Properties. Part II. Morphology
Felix Riewald, Philipp Kurzhals, Matteo Bianchini, Heino Sommer, Jürgen Janek, Hubert A. Gasteiger
Journal of the Electrochemical Society, 169, 2022

Multi‐Element Surface Coating of Layered Ni‐Rich Oxide Cathode Materials and Their Long‐Term Cycling Performance in Lithium‐Ion Batteries
Sören L. Dreyer, Katja R. Kretschmer, Đorđije Tripković, Andrey Mazilkin, Richard Chukwu, Raheleh Azmi, Pascal Hartmann, Matteo Bianchini, Torsten Brezesinski, Jürgen Janek
Advanced Materials Interfaces, 9, 2022

Real-Time Crystallization of LiCoO₂ from β-Co(OH)₂ and Co₃O₄ : Synthetic Pathways and Structural Evolution
Marie Duffiet, Damian Goonetilleke, François Fauth, Torsten Brezesinski, Jürgen Janek, Matteo Bianchini
Chemistry of Materials, 34, 9955-9969: 2022

Single step synthesis of W-modified LiNiO₂ using an ammonium tungstate flux
Damian Goonetilleke, Andrey Mazilkin, Daniel Weber, Yuan Ma, François Fauth, Jürgen Janek, Torsten Brezesinski, Matteo Bianchini
Journal of Materials Chemistry A, 10, 7841-7855: 2022

Single versus poly-crystalline layered oxide cathode materials for solid-state battery applications : a short review article
Seyedhosein Payandeh, Damian Goonetilleke, Matteo Bianchini, Jürgen Janek, Torsten Brezesinski
Current Opinion in Electrochemistry, 31, 2022

Single- to Few-Layer Nanoparticle Cathode Coating for Thiophosphate-Based All-Solid-State Batteries
Yuan Ma, Ruizhuo Zhang, Yushu Tang, Yanjiao Ma, Jun Hao Teo, Thomas Diemant, Damian Goonetilleke, Jürgen Janek, Matteo Bianchini, Aleksandr Kondrakov, Torsten Brezesinski
ACS Nano, 16, 18682-18694: 2022

Tracing Low Amounts of Mg in the Doped Cathode Active Material LiNiO₂
Daniel Weber, Jing Lin, Anuj Pokle, Kerstin Volz, Jürgen Janek, Torsten Brezesinski, Matteo Bianchini
Journal of the Electrochemical Society, 169, 2022

2021

Atomistic understanding of the LiNiO₂–NiO₂ phase diagram from experimentally guided lattice models
Markus Mock, Matteo Bianchini, François Fauth, Karsten Albe, Sabrina Sicolo
Journal of Materials Chemistry A, 9, 14928-14940: 2021

Cycling Performance and Limitations of LiNiO₂ in Solid-State Batteries
Yuan Ma, Jun Hao Teo, David Kitsche, Thomas Diemant, Florian Strauss, Yanjiao Ma, Damian Goonetilleke, Jürgen Janek, Matteo Bianchini, Torsten Brezesinski
ACS Energy Letters, 6, 3020-3028: 2021

Design-of-experiments-guided optimization of slurry-cast cathodes for solid-state batteries
Jun Hao Teo, Florian Strauss, Đorđije Tripković, Simon Schweidler, Yuan Ma, Matteo Bianchini, Jürgen Janek, Torsten Brezesinski
Cell Reports Physical Science, 2, 2021

High Performance All-Solid-State Batteries with a Ni-Rich NCM Cathode Coated by Atomic Layer Deposition and Lithium Thiophosphate Solid Electrolyte
David Kitsche, Yushu Tang, Yuan Ma, Damian Goonetilleke, Joachim Sann, Felix Walther, Matteo Bianchini, Jürgen Janek, Torsten Brezesinski
ACS Applied Energy Materials, 4, 7338-7345: 2021

The LiNiO₂ Cathode Active Material : A Comprehensive Study of Calcination Conditions and their Correlation with Physicochemical Properties. Part I. Structural Chemistry
Philipp Kurzhals, Felix Riewald, Matteo Bianchini, Heino Sommer, Hubert A. Gasteiger, Jürgen Janek
Journal of the Electrochemical Society, 168, 2021

Operando Characterization Techniques for All‐Solid‐State Lithium‐Ion Batteries
Florian Strauss, David Kitsche, Yuan Ma, Jun Hao Teo, Damian Goonetilleke, Jürgen Janek, Matteo Bianchini, Torsten Brezesinski
Advanced Energy & Sustainability Research, 2, 2021

Understanding the formation of antiphase boundaries in layered oxide cathode materials and their evolution upon electrochemical cycling
Shamail Ahmed, Anuj Pokle, Matteo Bianchini, Simon Schweidler, Andreas Beyer, Torsten Brezesinski, Jürgen Janek, Kerstin Volz
Matter, 4, 3953-3966: 2021

2020

And Yet It Moves : LiNiO₂, a Dynamic Jahn–Teller System
Sabrina Sicolo, Markus Mock, Matteo Bianchini, Karsten Albe
Chemistry of Materials, 32, 10096-10103: 2020

The effect of gallium substitution on the structure and electrochemical performance of LiNiO₂ in lithium-ion batteries
David Kitsche, Simon Schweidler, Andrey Mazilkin, Holger Geßwein, François Fauth, Emmanuelle Suard, Pascal Hartmann, Torsten Brezesinski, Jürgen Janek, Matteo Bianchini
Materials Advances, 1, 639-647: 2020

Enumeration as a Tool for Structure Solution : A Materials Genomic Approach to Solving the Cation-Ordered Structure of Na₃V₂(PO₄)₂F₃
Gerard S. Mattei, John M. Dagdelen, Matteo Bianchini, Alex M. Ganose, Anubhav Jain, Emmanuelle Suard, François Fauth, Christian Masquelier, Laurence Croguennec, Gerbrand Ceder, Kristin A. Persson, Peter G. Khalifah
Chemistry of Materials, 32, 8981-8992: 2020

From LiNiO₂ to Li₂NiO₃ : Synthesis, Structures and Electrochemical Mechanisms in Li-Rich Nickel Oxides
Matteo Bianchini, Alexander Schiele, Simon Schweidler, Sabrina Sicolo, François Fauth, Emmanuelle Suard, Sylvio Indris, Andrey Mazilkin, Peter Nagel, Stefan Schuppler, Michael Merz, Pascal Hartmann, Torsten Brezesinski, Jürgen Janek
Chemistry of Materials, 32, 9211-9227: 2020

In Situ Monitoring of Thermally Induced Effects in Nickel-Rich Layered Oxide Cathode Materials at the Atomic Level
Anuj Pokle, Shamail Ahmed, Simon Schweidler, Matteo Bianchini, Torsten Brezesinski, Andreas Beyer, Jürgen Janek, Kerstin Volz
ACS Applied Materials & Interfaces, 12, 57047-57054: 2020

An in situ structural study on the synthesis and decomposition of LiNiO₂
Matteo Bianchini, François Fauth, Pascal Hartmann, Torsten Brezesinski, Jürgen Janek
Journal of Materials Chemistry A, 8, 1808-1820: 2020

The interplay between thermodynamics and kinetics in the solid-state synthesis of layered oxides
Matteo Bianchini, Jingyang Wang, Raphaële J. Clément, Bin Ouyang, Penghao Xiao, Daniil Kitchaev, Tan Shi, Yaqian Zhang, Yan Wang, Haegyeom Kim, Mingjian Zhang, Jianming Bai, Feng Wang, Wenhao Sun, Gerbrand Ceder
Nature Materials, 19, 1088-1095: 2020

The Sound of Batteries : An Operando Acoustic Emission Study of the LiNiO₂ Cathode in Li–Ion Cells
Simon Schweidler, Matteo Bianchini, Pascal Hartmann, Torsten Brezesinski, Jürgen Janek
Batteries & Supercaps, 3, 1021-1027: 2020

Surface Modification Strategies for Improving the Cycling Performance of Ni‐Rich Cathode Materials
Daniel Weber, Đorđije Tripković, Katja Kretschmer, Matteo Bianchini, Torsten Brezesinski
European Journal of Inorganic Chemistry, 2020, 3117-3130: 2020

Visualization of Light Elements using 4D STEM : The Layered‐to‐Rock Salt Phase Transition in LiNiO₂ Cathode Material
Shamail Ahmed, Matteo Bianchini, Anuj Pokle, Manveer Singh Munde, Pascal Hartmann, Torsten Brezesinski, Andreas Beyer, Jürgen Janek, Kerstin Volz
Advanced Energy Materials, 10, 2020

2019

Computational Investigation and Experimental Realization of Disordered High-Capacity Li-Ion Cathodes Based on Ni Redox
Huiwen Ji, Daniil A. Kitchaev, Zhengyan Lun, Hyunchul Kim, Emily Foley, Deok-Hwang Kwon, Yaosen Tian, Mahalingam Balasubramanian, Matteo Bianchini, Zijian Cai, Raphaële J. Clément, Jae Chul Kim, Gerbrand Ceder
Chemistry of Materials, 31, 2431-2442: 2019

High Rate Performance for Carbon‐Coated Na₃V₂(PO₄)₂F₃ in Na‐Ion Batteries
Thibault Broux, François Fauth, Nikita Hall, Yohann Chatillon, Matteo Bianchini, Tahya Bamine, Jean‐Bernard Leriche, Emmanuelle Suard, Dany Carlier, Yvan Reynier, Loïc Simonin, Christian Masquelier, Laurence Croguennec
Small Methods, 3, 2019

The Role of Intragranular Nanopores in Capacity Fade of Nickel-Rich Layered Li(Ni₁₋ₓ₋ᵧCoₓMnᵧ)O₂ Cathode Materials
Shamail Ahmed, Anuj Pokle, Simon Schweidler, Andreas Beyer, Matteo Bianchini, Felix Walther, Andrey Mazilkin, Pascal Hartmann, Torsten Brezesinski, Jürgen Janek, Kerstin Volz
ACS Nano, 13, 10694-10704: 2019

There and Back Again : The Journey of LiNiO₂ as a Cathode Active Material
Matteo Bianchini, Maria Roca‐Ayats, Pascal Hartmann, Torsten Brezesinski, Jürgen Janek
Angewandte Chemie International Edition, 58, 10434-10458: 2019

2018

Ag₃V₂(PO₄)₂F₃, a new compound obtained by Ag⁺/Na⁺ ion exchange into the Na₃V₂(PO₄)₂F₃ framework
Matteo Bianchini, F. Lalère, H. B. L. Nguyen, François Fauth, R. David, Emmanuelle Suard, Laurence Croguennec, Christian Masquelier
Journal of Materials Chemistry A, 6, 10340-10347: 2018

A First‐Principles and Experimental Investigation of Nickel Solubility into the P2 NaₓCoO₂ Sodium‐Ion Cathode
Matteo Bianchini, Jingyang Wang, Raphaële J. Clément, Gerbrand Ceder
Advanced Energy Materials, 8, 2018

A New Strategy for High‐Voltage Cathodes for K‐Ion Batteries : Stoichiometric KVPO₄F
Haegyeom Kim, Dong‐Hwa Seo, Matteo Bianchini, Raphaële J. Clément, Hyunchul Kim, Jae Chul Kim, Yaosen Tian, Tan Shi, Won‐Sub Yoon, Gerbrand Ceder
Advanced Energy Materials, 8, 2018

Recent Progress and Perspective in Electrode Materials for K‐Ion Batteries
Haegyeom Kim, Jae Chul Kim, Matteo Bianchini, Dong‐Hwa Seo, Jorge Rodriguez‐Garcia, Gerbrand Ceder
Advanced Energy Materials, 8, 2018

2017

Additional Sodium Insertion into Polyanionic Cathodes for Higher-Energy Na-Ion Batteries
Matteo Bianchini, Penghao Xiao, Yan Wang, Gerbrand Ceder
Advanced Energy Materials, 7, 2017

2015

Comprehensive Investigation of the Na₃V₂(PO₄)₂F₃–NaV₂(PO₄)₂F₃ System by Operando High Resolution Synchrotron X-ray Diffraction
Matteo Bianchini, François Fauth, N. Brisset, F. Weill, Emmanuelle Suard, Christian Masquelier, Laurence Croguennec
Chemistry of Materials, 27, 3009-3020: 2015

Spinel materials for Li-ion batteries : new insights obtained by operando neutron and synchrotron X-ray diffraction
Matteo Bianchini, François Fauth, Emmanuelle Suard, Jean-Bernard Leriche, Christian Masquelier, Laurence Croguennec
Acta Crystallographica Section B, 71, 688-701: 2015

2014

Li-Rich Li₁₊ₓMn₂₋ₓO₄ Spinel Electrode Materials : An Operando Neutron Diffraction Study during Li⁺ Extraction/Insertion
Matteo Bianchini, Emmanuelle Suard, Laurence Croguennec, Christian Masquelier
The Journal of Physical Chemistry C, 118, 25947-25955: 2014

Multiple phases in the ε-VPO₄O–LiVPO₄O–Li₂VPO₄O system : a combined solid state electrochemistry and diffraction structural study
Matteo Bianchini, J. M. Ateba-Mba, P. Dagault, E. Bogdan, Dany Carlier, Emmanuelle Suard, Christian Masquelier, Laurence Croguennec
Journal of Materials Chemistry A, 2, 10182-10192: 2014

Na₃V₂(PO₄)₂F₃ Revisited : A High-Resolution Diffraction Study
Matteo Bianchini, N. Brisset, François Fauth, F. Weill, E. Elkaim, Emmanuelle Suard, Christian Masquelier, Laurence Croguennec
Chemistry of Materials, 26, 4238-4247: 2014

2013

A New Null Matrix Electrochemical Cell for Rietveld Refinements of In-Situ or Operando Neutron Powder Diffraction Data
Matteo Bianchini, J. B. Leriche, J.-L. Laborier, L. Gendrin, Emmanuelle Suard, Laurence Croguennec, Christian Masquelier
Journal of the Electrochemical Society, 160, 2013

2012

A tool to plan photon-in/photon-out experiments : count rates, dips and self-absorption
Matteo Bianchini, Pieter Glatzel
Journal of Synchrotron Radiation, 19, 911-919: 2012

Webmaster: Univ.Prof.Dr. Matteo Bianchini

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